Keeley J, Jarvis P, Smith AD, Judd SJ. Coagulant recovery and reuse for drinking water treatment. Water research 2015 Oct 21;88:502-509. doi:10.1016/j.watres.2015.10.038.
Coagulant recovery and reuse from waterworks sludge has the potential to significantly reduce waste disposal and chemicals usage for water treatment. Drinking water regulations demand purification of recovered coagulant before they can be safely reused, due to the risk of disinfection by-product precursors being recovered from waterworks sludge alongside coagulant metals. While several full-scale separation technologies have proven effective for coagulant purification, none have matched virgin coagulant treatment performance. This study examines the individual and successive separation performance of several novel and existing ferric coagulant recovery purification technologies to attain virgin coagulant purity levels. The new suggested approach of alkali extraction of dissolved organic compounds (DOC) from waterworks sludge prior to acidic solubilisation of ferric coagulants provided the same 14:1 selectivity ratio (874 mg/L Fe vs. 61 mg/L DOC) to the more established size separation using ultrafiltration (1285 mg/L Fe vs. 91 mg/L DOC). Cation exchange Donnan membranes were also examined: while highly selective (2555 mg/L Fe vs. 29 mg/L DOC, 88:1 selectivity), the low pH of the recovered ferric solution impaired subsequent treatment performance. The application of powdered activated carbon (PAC) to ultrafiltration or alkali pre-treated sludge, dosed at 80 mg/mg DOC, reduced recovered ferric DOC contamination to <1 mg/L but in practice, this option would incur significant costs. The treatment performance of the purified recovered coagulants was compared to that of virgin reagent with reference to key water quality parameters. Several PAC-polished recovered coagulants provided the same or improved DOC and turbidity removal as virgin coagulant, as well as demonstrating the potential to reduce disinfection byproducts and regulated metals to levels comparable to that attained from virgin material.
Sun Y, Fan W, Zheng H, Zhang Y, Li F, Chen W. Evaluation of Dewatering Performance and Fractal Characteristics of Alum Sludge. PloS one.” 2015 Jun 29;10(6):e0130683. doi: 10.1371/journal.pone.0130683.
The dewatering performance and fractal characteristics of alum sludge from a drinking-water treatment plant were investigated in this study. Variations in residual turbidity of supernatant, dry solid content (DS), specific resistance to filtration (SRF), floc size, fractal dimension, and zeta potential were analyzed. Sludge dewatering efficiency was evaluated by measuring both DS and SRF. Results showed that the optimum sludge dewatering efficiency was achieved at 16 mg∙L-1 flocculant dosage and pH 7. Under these conditions, the maximum DS was 54.6%, and the minimum SRF was 0.61 × 1010 m∙kg-1. Floc-size measurements demonstrated that high flocculant dosage significantly improved floc size. Correlation analysis further revealed a strong correlation between fractal dimension and floc size after flocculation. A strong correlation also existed between floc size and zeta potential, and flocculants with a higher cationic degree had a larger correlation coefficient between floc size and zeta potential. In the flocculation process, the main flocculation mechanisms involved adsorption bridging under an acidic condition, and a combination between charge neutralization and adsorption-bridging interaction under neutral and alkaline conditions.
Posted in Residuals
Dassanayake KB, Jayasinghe GY, Surapaneni A, Hetherington C. A review on alum sludge reuse with special reference to agricultural applications and future challenges. Waste Management (New York, N.Y.) 2015 Feb 2
Alum salts are commonly used in the water industry to promote coagulation in the production of clean drinking water, which results in the generation and accumulation of ‘waste’ by-product ‘alum sludge’ in large volumes. Effective and efficient management of alum sludge in an economically and environmentally sustainable manner remains a significant social and environmental concern with ever increasing demand for potable water as a result of rapidly escalating world population and urban expansion. Various intensive practices have been employed to reuse the alum sludge in an attempt to figure out how to fill the gap between successful drinking water treatment process and environmentally friendly alum sludge management for over the years. This paper primarily aimed at comprehensive review of the existing literature on alum sludge characteristics, its environmental concerns and their potential utilization, especially in agricultural and horticultural sectors leading to update our recent state of knowledge and formulate a compendium of present and past developments. Different types of alum sludge utilizations in various fields were recognized and examined. The strengths, weaknesses, opportunities and potential risks of alum sludge reuse options with particular reference to agriculture were highlighted and knowledge gaps were identified. Research priorities and future challenges that will support in the development of effective alum sludge management practices in agriculture with multi-prong strategies were discussed.
Zhiwei Zhou, Yanling Yang, Xing Li, Yang Zhang, Xuan Guo. Characterization of drinking water treatment sludge after ultrasound treatment. Ultrasonics – Sonochemistry May 2015 24:19-26
Ultrasonic technology alone or the combination of ultrasound with alkaline or thermal hydrolysis as pretreatment for anaerobic digestion of activated sludge has been extensively documented. However, there are few reports on ultrasound as pretreatment of drinking water treatment sludge (DWTS), and thereby the characteristic variability of sonicated DWTS has not been fully examined. This research presents a lab-scale study on physical, chemical and biological characteristics of a DWTS sample collected from a water plant after ultrasonic treatment via a bath/probe sonoreactor. By doing this work, we provide implications for using ultrasound as pretreatment of enhanced coagulation of recycling sludge, and for the conditioning of water and wastewater mixed sludge by ultrasound combined with polymers. Our results indicate that the most vigorous DWTS disintegration quantified by particles’ size reduction and organic solubilization is achieved with 5W/ml for 30min ultra-sonication (specific energy of 1590kWh/kgTS). The Brunauer, Emmett and Teller (BET) specific surface area of sonicated DWTS flocs increase as ultra-sonication prolongs at lower energy densities (0.03 and 1W/ml), while decrease as ultra-sonication prolongs at higher energy densities (3 and 5W/ml). Additionally, the pH and zeta potential of sonicated DWTS slightly varies under all conditions observed. A shorter sonication with higher energy density plays a more effective role in restraining microbial activity than longer sonication with lower energy density.
Posted in Residuals
E.Fonollosa, A. Nieto, A. Peñalver, C. Aguilar, and F. Borrull. Presence of radionuclides in sludge from conventional drinking water treatment plants; A review. Journal of Environmental Radioactivity. March 2015 141:24-31
The analysis of sludge samples generated during water treatment processes show that different radioisotopes of uranium, thorium and radium, among others can accumulate in that kind of samples, even the good removal rates obtained in the aqueous phase (by comparison of influent and effluent water concentrations). Inconsequence, drinking water treatment plants are included in the group of Naturally Occurring Radioactive Material (NORM) industries. The accumulation of radionuclides can be a serious problem especially when this sludge is going to be reused, so more exhaustive information is required to prevent the possible radiological impact of these samples in the environment and also on the people. The main aim of this review is to outline the current situation regarding the different studies reported in the literature up to date focused on the analysis of the radiological content of these sludge samples from drinking water treatment plants. In this sense, special attention is given to the recent approaches for their determination. Another important aim is to discuss about the final disposal of these samples and in this regard, sludge reuse (including for example direct agricultural application or also as building materials) are together with landfilling the main reported strategies.
Posted in Residuals
Habibiandehkordi R, Quinton JN, Surridge BW. Long-term effects of drinking-water treatment residuals on dissolved phosphorus export from vegetated buffer strips. Environmental science and pollution research international. 2014 Nov 13.
The export of dissolved phosphorus (P) in surface runoff from agricultural land can lead to water quality degradation. Surface application of aluminium (Al)-based water treatment residuals (Al-WTRs) to vegetated buffer strip (VBS) soils can enhance P removal from surface runoff during single runoff events. However, the longer-term effects on P removal in VBSs following application of products such as Al-WTR remain uncertain. We used field experimental plots to examine the long-term effects of applying a freshly generated Al-WTR to VBSs on dissolved P export during multiple runoff events, occurring between 1 day and 42 weeks after the application of Al-WTR. Vegetated buffer strip plots amended with Al-WTR significantly reduced soluble reactive P and total dissolved P concentrations in surface runoff compared to both unamended VBS plots and control plots. However, the effectiveness of Al-WTR decreased over time, by approximately 70 % after 42 weeks compared to a day following Al-WTR application. Reduced performance did not appear to be due to drying of Al-WTR in the field. Instead, the development of preferential flow paths as well as burying of Al-WTR with freshly deposited sediments may explain these observations. Better understanding of the processes controlling long-term P removal by Al-WTR is required for effective management of VBSs.
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